When materials such as black iron (BI) cast iron (CI) and ductile iron (DI) are interconnected. they are very close together in the electromotive series of metals and therefore, each would suffer very little additional corrosion by connecting to the other metal. When a dissimilar metal couple is created by connecting BI, Cl, or DI to copper or brass a significant corrosion cell is created.
Copper is electropositive with respect to all ferrous construction materials. In addition copper will not polarize readily as is the case for ferrous structures. Therefor
accelerated corrosion is the result on ferrous structures whenever they are directly coupled to bare copper in the soil.
Tinning of copper has been tried by some utilities, that reduces the corrosion cell with respect to steel and zinc by about 5O% and practically eliminates this potential with respect to lead.
Most electrical engineers specify copper for grounding grid since it is the preferred material of choice for electrical conductivity. However, when copper is directly burried in the soil and completely isolated from other construction materials, it will corrode.
In acidic soil conditions, the corrosion rate of copper may be greater than that of iron or steel.
Aluminium has been used for ground grid less frequently. Though at first glance the use of aluminum would seem to be a natural choice for gas insulated substation (GIS), equipment since the enclosures are made of aluminum or aluminum alloys.
Steel has been used for ground-grid conductors in many european countries mainly for the benefit of eliminating most of the adverse effects of copper already mentioned.
Application of galvanized or stainless steel in combination with cathodic protection is typical.
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